Discrete and encapsulated molecular grids: homometallic Mn15 and heterometallic Mn24Ni2 aggregates.

نویسندگان

  • Maria Charalambous
  • Sotiris M Zartilas
  • Eleni E Moushi
  • Constantina Papatriantafyllopoulou
  • Manolis J Manos
  • Theocharis C Stamatatos
  • Shreya Mukherjee
  • Vassilios Nastopoulos
  • George Christou
  • Anastasios J Tasiopoulos
چکیده

Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with the former one being among the highest nuclearity heterometallic MnxMy clusters (M = any transition metal ion).

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عنوان ژورنال:
  • Chemical communications

دوره 50 65  شماره 

صفحات  -

تاریخ انتشار 2014